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Issue 19, 2015
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Photocontrolled chignolin-derived β-hairpin peptidomimetics

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Abstract

The synthesis of novel, chignolin-derived peptides comprising the azobenzene photoswitch [3-(3-aminomethyl)phenylazo]phenylacetic acid (AMPP) is reported. Reversible photoswitching behavior led to folding into β-hairpin-like structures, as unequivocally demonstrated by CD, FT-IR and NMR spectroscopy.

Graphical abstract: Photocontrolled chignolin-derived β-hairpin peptidomimetics

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Supplementary files

Article information


Submitted
24 Dec 2014
Accepted
19 Jan 2015
First published
19 Jan 2015

This article is Open Access

Chem. Commun., 2015,51, 4001-4004
Article type
Communication
Author version available

Photocontrolled chignolin-derived β-hairpin peptidomimetics

T. Podewin, M. S. Rampp, I. Turkanovic, K. L. Karaghiosoff, W. Zinth and A. Hoffmann-Röder, Chem. Commun., 2015, 51, 4001
DOI: 10.1039/C4CC10304A

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