A rhodium-catalysed direct C–H allylation of readily accessible N-sulfonyl ketimines with various allyl carbonates has successfully been achieved. The computational studies indicated that olefin insertion and β-oxygen elimination steps were involved in the catalytic cycle.
S. Mei, N. Wang, Q. Ouyang and Y. Wei, Chem. Commun., 2015, 51, 2980 DOI: 10.1039/C4CC09899D
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