A nanostructured CeO2 promoted Pd/α-alumina diethyl oxalate catalyst with high activity and stability

Erlei Jin; Leilei He; Yulong zhang; Anthony R. Richard; Maohong Fan

doi:10.1039/C4RA08170F

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A nanostructured CeO₂ promoted Pd/α-alumina diethyl oxalate catalyst with high activity and stability†

Erlei Jin,^a Leilei He,^a Yulong zhang,^b Anthony R. Richard^a and Maohong Fan*^ac

Author affiliations

* Corresponding authors

^a Department of Chemical and Petroleum Engineering, University of Wyoming, Laramie, WY 82071, USA
E-mail: mfan@uwyo.edu

^b Western Research Institute, Laramie, WY 82070, USA

^c School of Energy Resources, University of Wyoming, Laramie, WY 82071, USA

Abstract

A Pd/α-Al₂O₃ nanocatalyst was synthesized and investigated as a catalyst for CO oxidative coupling to diethyl oxalate and CeO₂ was used as a promoter. With the highest activity and stability found so far, great CO conversion and diethyl oxalate selectivity were achieved due to the addition of CeO_2.

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Article information

DOI: https://doi.org/10.1039/C4RA08170F
Article type: Communication
Submitted: 05 Aug 2014
Accepted: 23 Sep 2014
First published: 24 Sep 2014

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RSC Adv., 2014,4, 48901-48904

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A nanostructured CeO₂ promoted Pd/α-alumina diethyl oxalate catalyst with high activity and stability

E. Jin, L. He, Y. zhang, A. R. Richard and M. Fan, RSC Adv., 2014, 4, 48901 DOI: 10.1039/C4RA08170F

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