Issue 71, 2014

Copper catalysed [3 + 2] cycloaddition with concomitant annulation: formation of 2,4-diaryl-1,4-oxazepan-7-ones via a ketenimine route

Abstract

A novel strategy for a copper catalyzed cascade reaction involving intramolecular nucleophilic addition to N-sulfonylketenimine gratifyingly furnishing 1,4-diaryl oxazepan-7-one has been described.

Graphical abstract: Copper catalysed [3 + 2] cycloaddition with concomitant annulation: formation of 2,4-diaryl-1,4-oxazepan-7-ones via a ketenimine route

Supplementary files

Article information

Article type
Communication
Submitted
08 Jul 2014
Accepted
12 Aug 2014
First published
12 Aug 2014

RSC Adv., 2014,4, 37526-37528

Author version available

Copper catalysed [3 + 2] cycloaddition with concomitant annulation: formation of 2,4-diaryl-1,4-oxazepan-7-ones via a ketenimine route

S. Kaladevi, A. Thirupathi, J. Sridhar and S. Muthusubramanian, RSC Adv., 2014, 4, 37526 DOI: 10.1039/C4RA08008D

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