Bianthrones have occurred widely in drug and material developments, but the stereochemistry remains in chaos so far due to the meso, racemic, and axis-rotating phenomena. Based on the computational and experimental results, an effective rule to distinguish between cis and trans bianthrones by 1H NMR is concluded, which applies to both homo- and heterobianthrones.
N. Ji, X. Liang, R. Sun and F. Miao, RSC Adv., 2014, 4, 7710 DOI: 10.1039/C3RA47055E
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