Issue 6, 2014
From the journal:

Organic Chemistry Frontiers

A green fullerene derivative as a fluoride ion sensor†

Liang Xu,a   Sisi Lianga  and  Liangbing Gan*ab  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
E-mail: gan@pku.edu.cn

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China

Abstract

An open-cage fullerene derivative with an enamine moiety on the rim of the orifice is prepared through a lithium chloride induced dehydration process involving an intramolecular Friedel–Crafts reaction and ring expansion rearrangement steps. The enamine moiety reacts with fluoride ions selectively and acts as the active site for fluoride ion detection.

Graphical abstract: A green fullerene derivative as a fluoride ion sensor

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Article information

DOI
https://doi.org/10.1039/C4QO00111G
Article type
Research Article
Submitted
16 Apr 2014
Accepted
04 May 2014
First published
05 May 2014

Org. Chem. Front., 2014,1, 652-656

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A green fullerene derivative as a fluoride ion sensor

L. Xu, S. Liang and L. Gan, Org. Chem. Front., 2014, 1, 652 DOI: 10.1039/C4QO00111G

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