Oxidation and reduction processes of platinum nanoparticles observed at the atomic scale by environmental transmission electron microscopy

Abstract

Oxidation and reduction of the surfaces of Pt nanoparticles were in situ examined in reactive gases (O₂, CO and H₂O vapor) by aberration-corrected environmental transmission electron microscopy. Atomic layers of Pt oxides were gradually formed on the surface of Pt nanoparticles at room temperature in O₂. The surface Pt oxides were reduced to Pt promptly in both vacuum and gas including CO. We showed that H₂O vapor suppressed the surface oxidation. The processes found in this study were induced by gases that were most likely activated by electron irradiation. The observation results provide atomistic insight into the oxidation and reduction process of the surface of Pt nanoparticles that is exposed to activated gases.