A Ti3+:TiO2/TiF3 hybrid with enhanced visible-light photocatalytic reactivity

Xiaodong Meng; Baibiao Huang; Xiangchao Ma; Zeyan Wang; Zhaoke Zheng; Junpeng Wang; Xiaoyan Qin; Xiaoyang Zhang; Ying Dai

doi:10.1039/C4CE00569D

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A Ti³⁺:TiO₂/TiF₃ hybrid with enhanced visible-light photocatalytic reactivity†

Xiaodong Meng,^a Baibiao Huang,*^a Xiangchao Ma,^b Zeyan Wang,*^a Zhaoke Zheng,^a Junpeng Wang,^a Xiaoyan Qin,^a Xiaoyang Zhang^a and Ying Dai^b

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* Corresponding authors

^a State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China
E-mail: bbhuang@sdu.edu.cn, wangzeyan@sdu.edu.cn

^b School of Physics, Shandong University, Jinan 250100, China

Abstract

A Ti³⁺:TiO₂/TiF₃ hybrid was synthesized via a one-step facile solvothermal method. Due to the presence of TiF₃, TiO₂ contained a high concentration of Ti³⁺ species and Ti³⁺ was stabilized. The Ti³⁺:TiO₂/TiF₃ hybrid exhibited excellent visible-light photocatalytic reactivity. The electron structure of TiF₃ was studied, and a photocatalytic mechanism was also proposed.

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Article information

DOI: https://doi.org/10.1039/C4CE00569D
Article type: Communication
Submitted: 19 Mar 2014
Accepted: 29 Apr 2014
First published: 29 Apr 2014

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CrystEngComm, 2014,16, 6538-6541

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A Ti³⁺:TiO₂/TiF₃ hybrid with enhanced visible-light photocatalytic reactivity

X. Meng, B. Huang, X. Ma, Z. Wang, Z. Zheng, J. Wang, X. Qin, X. Zhang and Y. Dai, CrystEngComm, 2014, 16, 6538 DOI: 10.1039/C4CE00569D

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