Issue 100, 2014

Two act as one: unexpected dimers of catechol direct a solid-state [2+2] photodimerization in a six-component hydrogen-bonded assembly

Abstract

We describe hydrogen-bonded dimers of catechol that act collectively as a single template to direct an intermolecular [2+2] photocycloaddition in the solid state. The directed reactivity involves discrete, six-component hydrogen-bonded assemblies and a photoreaction that occurs stereoselectively and in quantitative yield.

Graphical abstract: Two act as one: unexpected dimers of catechol direct a solid-state [2+2] photodimerization in a six-component hydrogen-bonded assembly

Supplementary files

Article information

Article type
Communication
Submitted
30 Sep 2014
Accepted
29 Oct 2014
First published
31 Oct 2014

Chem. Commun., 2014,50, 15960-15962

Author version available

Two act as one: unexpected dimers of catechol direct a solid-state [2+2] photodimerization in a six-component hydrogen-bonded assembly

G. S. Papaefstathiou, A. J. E. Duncan and L. R. MacGillivray, Chem. Commun., 2014, 50, 15960 DOI: 10.1039/C4CC07747D

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