Issue 98, 2014
From the journal:

Chemical Communications

Self-assembly of NIR luminescent 30-metal drum-like and 12-metal rectangular d–f nanoclusters with long-chain Schiff base ligands†

Xiaoping Yang,*ab   Zongping Li,ab   Shiqing Wang,ab   Shaoming Huang,*ab   Desmond Schipperc  and  Richard A. Jones*c  

* Corresponding authors

a College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China
E-mail: xpyang@wzu.edu.cn, smhuang@wzu.edu.cn
Tel: 86 577 88373064

b Zhejiang Key Laboratory of Carbon Materials, Wenzhou 325035, China

c The University of Texas at Austin, Department of Chemistry and Biochemistry, 1 University Station A5300, Austin, Texas, USA
E-mail: rajones@cm.utexas.edu
Tel: +1-512-4711706

Abstract

Two classes of heterobimetallic d–f nanoclusters [Ln6Cd24(L1)11(OAc)43(OH)] and [Ln4Zn8(L2)2(OAc)20(OH)4] (Ln = Nd and Yb) were prepared using flexible long-chain Schiff base ligands which have (CH2)6 backbones. Their NIR luminescence properties were determined.

Graphical abstract: Self-assembly of NIR luminescent 30-metal drum-like and 12-metal rectangular d–f nanoclusters with long-chain Schiff base ligands

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Article information

DOI
https://doi.org/10.1039/C4CC07174C
Article type
Communication
Submitted
11 Sep 2014
Accepted
21 Oct 2014
First published
21 Oct 2014

Chem. Commun., 2014,50, 15569-15572

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Self-assembly of NIR luminescent 30-metal drum-like and 12-metal rectangular d–f nanoclusters with long-chain Schiff base ligands

X. Yang, Z. Li, S. Wang, S. Huang, D. Schipper and R. A. Jones, Chem. Commun., 2014, 50, 15569 DOI: 10.1039/C4CC07174C

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