SCHEDULED MAINTENANCE
While purifying new polysubstituted 5-nitrosopyrimidines, the unique separation of pairs of rotamers as chemical species, stabilized by a single intramolecular hydrogen bond and differing only in nitroso group orientation, was achieved. This interesting stereochemical phenomenon is compared to the well-known atropisomerism.
L. Čechová, E. Procházková, I. Císařová, M. Dračínský and Z. Janeba, Chem. Commun., 2014, 50, 14892 DOI: 10.1039/C4CC06978A
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