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Issue 96, 2014
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Magnetic blocking in extended metal atom chains: a pentachromium(ii) complex behaving as a single-molecule magnet

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Abstract

Compound [Cr5(tpda)4Cl2] (H2tpda = N2,N6-di(pyridin-2-yl)pyridine-2,6-diamine), an Extended Metal Atom Chain complex featuring two quadruply-bonded {Cr2} units, exhibits field-induced slow relaxation of its magnetization arising from the terminal chromium(II) ion and provides the first example of a chromium(II)-based Single-Molecule Magnet.

Graphical abstract: Magnetic blocking in extended metal atom chains: a pentachromium(ii) complex behaving as a single-molecule magnet

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Supplementary files

Article information


Submitted
25 Aug 2014
Accepted
08 Oct 2014
First published
09 Oct 2014

This article is Open Access

Chem. Commun., 2014,50, 15191-15194
Article type
Communication

Magnetic blocking in extended metal atom chains: a pentachromium(II) complex behaving as a single-molecule magnet

A. Cornia, L. Rigamonti, S. Boccedi, R. Clérac, M. Rouzières and L. Sorace, Chem. Commun., 2014, 50, 15191
DOI: 10.1039/C4CC06693F

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