Issue 90, 2014
From the journal:

Chemical Communications

Versatile palladium-catalyzed C–H olefination of (hetero)arenes at room temperature†

Zhijie She,a   Yang Shi,a   Yumin Huang,a   Yangyang Cheng,a   Feijie Song*a  and  Jingsong You*a  

* Corresponding authors

a Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P. R. China
E-mail: jsyou@scu.edu.cn, fsong@scu.edu.cn
Fax: +86 28-85412203

Abstract

The room-temperature oxidative C–H/C–H cross-couplings between (hetero)arenes and alkenes, coumarins or quinones have been reported by using a highly electrophilic palladium species [Pd(TFA)2], generated in situ from Pd(OAc)2 and TFA, as the catalyst and cheap (NH4)2S2O8 as the oxidant under air.

Graphical abstract: Versatile palladium-catalyzed C–H olefination of (hetero)arenes at room temperature

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Article information

DOI
https://doi.org/10.1039/C4CC05827E
Article type
Communication
Submitted
27 Jul 2014
Accepted
15 Sep 2014
First published
17 Sep 2014

Chem. Commun., 2014,50, 13914-13916

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Versatile palladium-catalyzed C–H olefination of (hetero)arenes at room temperature

Z. She, Y. Shi, Y. Huang, Y. Cheng, F. Song and J. You, Chem. Commun., 2014, 50, 13914 DOI: 10.1039/C4CC05827E

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