Cyclic voltammetry has been used for the first time to probe and to control the formation of non-covalent halogen bonding (XB) via redox switching. These results strongly encourage the use of electrochemistry as an economical and precisely controllable tool for the investigation of XB in solution.
S. Groni, T. Maby-Raud, C. Fave, M. Branca and B. Schöllhorn, Chem. Commun., 2014, 50, 14616 DOI: 10.1039/C4CC04134H
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