Expeditious selective access to functionalized platforms of A7B-type heteroleptic lanthanide double-decker complexes of phthalocyanine

Serkan Alpugan; Ümit İşci; Florian Albrieux; Catherine Hirel; Ayşe Gül Gürek; Yann Bretonnière; Vefa Ahsen; Fabienne Dumoulin

doi:10.1039/C4CC02523G

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Expeditious selective access to functionalized platforms of A₇B-type heteroleptic lanthanide double-decker complexes of phthalocyanine†

Serkan Alpugan,^a Ümit İşci,^a Florian Albrieux,^b Catherine Hirel,^a Ayşe Gül Gürek,^a Yann Bretonnière,^c Vefa Ahsen^a and Fabienne Dumoulin*^a

Author affiliations

* Corresponding authors

^a Gebze Institute of Technology, Faculty of Sciences, Department of Chemistry, 41400, Gebze, Kocaeli, Turkey
E-mail: fdumoulin@gyte.edu.tr
Fax: +902626053005
Tel: +902626053022

^b Centre Commun de Spectrométrie de Masse UMR 5246, CNRS-Claude Bernard Lyon 1, Université de Lyon, Bâtiment Curien, 43, bd du 11 Novembre, Université 69622 Villeurbanne Cedex, France

^c ENS Lyon, Université de Lyon, Laboratoire de Chimie de l'ENS Lyon, UMR 5182 CNRS-ENS Lyon, 46 allée d'Italie, 69364 Lyon, France

Abstract

A one-step method to access to functionalized heteroleptic lanthanide double-decker complexes of phthalocyanine of A₇B-type is reported. This optimized statistical method led to two hydroxylated model europium complexes, one of which was further converted into its mesylated and azido derivatives.

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Article information

DOI: https://doi.org/10.1039/C4CC02523G
Article type: Communication
Submitted: 06 Apr 2014
Accepted: 02 May 2014
First published: 06 May 2014

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Chem. Commun., 2014,50, 7466-7468

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Expeditious selective access to functionalized platforms of A₇B-type heteroleptic lanthanide double-decker complexes of phthalocyanine

S. Alpugan, Ü. İşci, F. Albrieux, C. Hirel, A. G. Gürek, Y. Bretonnière, V. Ahsen and F. Dumoulin, Chem. Commun., 2014, 50, 7466 DOI: 10.1039/C4CC02523G

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Chemical Communications