Issue 57, 2014
From the journal:

Chemical Communications

Complex thermal expansion properties in a molecular honeycomb lattice†

Jonathan J. Loughrey,‡a   Tim P. Comyn,b   David C. Apperley,c   Marc A. Little§a  and  Malcolm A. Halcrow*a  

* Corresponding authors

a School of Chemistry, University of Leeds, Leeds, UK LS2 9JT
E-mail: m.a.halcrow@leeds.ac.uk
Fax: +44 (0)113 343 6565
Tel: +44 (0)113 343 6506

b Institute for Materials Research, School of Process, Environmental and Materials Engineering, University of Leeds, Leeds, UK LS2 9JT

c EPSRC Solid State NMR Service, Department of Chemistry, University of Durham, South Road, Durham, UK DH1 3LE

Abstract

[FeL3][BF4]2·xH2O (L = 3-(pyrazinyl)-1H-pyrazole) shows negative thermal expansion between 150–240 K but positive thermal expansion at 240–300 K, linked to rearrangement of anions and water molecules within pores in the lattice.

Graphical abstract: Complex thermal expansion properties in a molecular honeycomb lattice

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Article information

DOI
https://doi.org/10.1039/C4CC02198C
Article type
Communication
Submitted
25 Mar 2014
Accepted
22 May 2014
First published
29 May 2014

Chem. Commun., 2014,50, 7601-7603

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Complex thermal expansion properties in a molecular honeycomb lattice

J. J. Loughrey, T. P. Comyn, D. C. Apperley, M. A. Little and M. A. Halcrow, Chem. Commun., 2014, 50, 7601 DOI: 10.1039/C4CC02198C

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