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Issue 54, 2014
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A stable metallic state of (TTPCOO)2NH4 with a mobile dopant

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Abstract

Ammonium tetrathiapentalene carboxylate [(TTPCOO)2NH4] was prepared via protonic defect-induction doping without electrochemical oxidation. The high electric conductivity of 13 S cm−1 and Pauli paramagnetic-like behavior of magnetic susceptibility in a wide temperature range exhibit a melting of the charge degrees of freedom induced by a mobile dopant in a salt bridge. Solid-state 1H NMR strongly indicates a stable metallic state of this compound down to 4 K.

Graphical abstract: A stable metallic state of (TTPCOO)2NH4 with a mobile dopant

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Submitted
27 Jan 2014
Accepted
13 Mar 2014
First published
27 Mar 2014

Chem. Commun., 2014,50, 7111-7113
Article type
Communication

A stable metallic state of (TTPCOO)2NH4 with a mobile dopant

T. Terauchi, S. Sumi, Y. Kobayashi, T. Nakamura, K. Furukawa and Y. Misaki, Chem. Commun., 2014, 50, 7111
DOI: 10.1039/C4CC00678J

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