Issue 19, 2013
From the journal:

Journal of Materials Chemistry A

High pressure, high temperature electrochemical synthesis of metal–organic frameworks: films of MIL-100 (Fe) and HKUST-1 in different morphologies†

Nicolò Campagnol,a   Tom Van Assche,b   Tom Boudewijns,c   Joeri Denayer,b   Koen Binnemans,d   Dirk De Vos*c  and  Jan Fransaer*a  

* Corresponding authors

a Department of Metallurgy and Materials Engineering (MTM), KU Leuven – University of Leuven, Kasteelpark Arenberg 44, B-3001 Leuven, Belgium
E-mail: Jan.Fransaer@mtm.kuleuven.be

b Department of Chemical Engineering, Vrije Universiteit Brussel, B-1050 Brussels, Belgium

c Centre for Surface Chemistry and Catalysis (COK), KU Leuven – University of Leuven, Kasteelpark Arenberg 23, B-3001 Leuven, Belgium
E-mail: Dirk.DeVos@biw.kuleuven.be

d Department of Chemistry, KU Leuven – University of Leuven, B-3001 Leuven, Belgium

Abstract

Thanks to a new high temperature electrodeposition setup, MIL-100(Fe) is synthesized and deposited electrochemically for the first time. In comparison to other methods commonly used to produce this MOF, the reported synthesis allows formation of layers, and it takes place under milder conditions. The layers have been tested for anti-fouling, gas adsorption and vapor separation. With the same setup Cu–BTC MOF HKUST-1 has been deposited at different temperatures obtaining different morphologies.

Graphical abstract: High pressure, high temperature electrochemical synthesis of metal–organic frameworks: films of MIL-100 (Fe) and HKUST-1 in different morphologies

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Article information

DOI
https://doi.org/10.1039/C3TA10419B
Article type
Communication
Submitted
28 Jan 2013
Accepted
19 Mar 2013
First published
20 Mar 2013

J. Mater. Chem. A, 2013,1, 5827-5830

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High pressure, high temperature electrochemical synthesis of metal–organic frameworks: films of MIL-100 (Fe) and HKUST-1 in different morphologies

N. Campagnol, T. Van Assche, T. Boudewijns, J. Denayer, K. Binnemans, D. De Vos and J. Fransaer, J. Mater. Chem. A, 2013, 1, 5827 DOI: 10.1039/C3TA10419B

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