A sulfur rich electron acceptor and its [Fe(Cp*)2]+ charge transfer salt with ferromagnetic interactions

Yann Le Gal; Nathalie Bellec; Frédéric Barrière; Rodolphe Clérac; Marc Fourmigué; Vincent Dorcet; Thierry Roisnel; Dominique Lorcy

doi:10.1039/C3DT52725E

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A sulfur rich electron acceptor and its [Fe(Cp*)₂]⁺ charge transfer salt with ferromagnetic interactions†

Yann Le Gal,^a Nathalie Bellec,^a Frédéric Barrière,^a Rodolphe Clérac,^bc Marc Fourmigué,^a Vincent Dorcet,^a Thierry Roisnel^a and Dominique Lorcy*^a

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* Corresponding authors

^a Institut des Sciences Chimiques de Rennes, Université de Rennes 1, CNRS UMR 6226, Matière Condensée et Systèmes Electroactifs (MaCSE), Campus de Beaulieu, Bât 10A, 35042 Rennes cedex, France
E-mail: dominique.lorcy@univ-rennes1.fr
Fax: (+33)-2-23-23-67-38

^b CNRS, CRPP, UPR 8641, F-33600 Pessac, France

^c Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France

Abstract

The study of a side product of the aerial dithiolene oxidation allowed the rational and efficient synthesis of a sulfur rich electron acceptor, (E)-3,3′-diethyl-5,5′-bithiazolidinylidene-2,4,2′,4′-tetrathione, that presents easily accessible redox states and forms with decamethylferrocene a charge transfer salt exhibiting ferromagnetic coupling.

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DOI: https://doi.org/10.1039/C3DT52725E
Article type: Communication
Submitted: 23 Jul 2013
Accepted: 03 Oct 2013
First published: 03 Oct 2013

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Dalton Trans., 2013,42, 16672-16675

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A sulfur rich electron acceptor and its [Fe(Cp*)₂]⁺ charge transfer salt with ferromagnetic interactions

Y. Le Gal, N. Bellec, F. Barrière, R. Clérac, M. Fourmigué, V. Dorcet, T. Roisnel and D. Lorcy, Dalton Trans., 2013, 42, 16672 DOI: 10.1039/C3DT52725E

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Dalton Transactions