Issue 20, 2013
From the journal:

Dalton Transactions

N-Heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation†

David Gatineau,a   Qiwu Zhao,a   Dennis P. Curran,b   Max Malacria,a   Emmanuel Lacôte,c   Louis Fensterbank*a  and  Jean-Philippe Goddard*a  

* Corresponding authors

a Institut Parisien de Chimie Moléculaire (UMR CNRS 7201)-FR 2769 UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris, France
E-mail: louis.fensterbank@upmc.fr, jean-philippe.goddard@upmc.fr
Fax: (+33) 1-44-27-73-60

b Department of Chemistry, University of Pittsburgh, 4200 Fifth Avenue, Pittsburgh, Pennsylvania 15260, USA

c Université de Lyon, Institut de chimie de Lyon UMR 5265 CNRS-Université Lyon I-ESCPE Lyon, 43 Bd du 11 novembre 1918, 69616 Villeurbanne, France

Abstract

Investigation of the mechanism of the NHC-initiated hydrosilylation of styryl alcohols in the presence of a dihydrosilane suggests a general base catalysis mechanism and not the activation of the dihydrosilane by the NHC.

Graphical abstract: N-Heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation

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Article information

DOI
https://doi.org/10.1039/C3DT32983F
Article type
Paper
Submitted
12 Dec 2012
Accepted
08 Feb 2013
First published
08 Feb 2013

Dalton Trans., 2013,42, 7458-7462

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N-Heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation

D. Gatineau, Q. Zhao, D. P. Curran, M. Malacria, E. Lacôte, L. Fensterbank and J. Goddard, Dalton Trans., 2013, 42, 7458 DOI: 10.1039/C3DT32983F

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