Issue 68, 2013
From the journal:

Chemical Communications

Palladium-catalyzed desulfitative hydroarylation of alkynes with sodium sulfinates†

Saiwen Liu,a   Yang Bai,a   Xiangxiang Cao,a   Fuhong Xiaoa  and  Guo-Jun Deng*ab  

* Corresponding authors

a Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, China
E-mail: gjdeng@xtu.edu.cn
Fax: +86 0731-5829-2251
Tel: +86 0731-5829-8601

b Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China

Abstract

A palladium-catalyzed desulfitative hydroarylation of alkynes with aryl sulfinic acid sodium salts is described. The reaction showed good regio- and stereoselectivity, and afforded the hydroarylation products in good yields. Various functional groups were well tolerated under the optimized reaction conditions.

Graphical abstract: Palladium-catalyzed desulfitative hydroarylation of alkynes with sodium sulfinates

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Article information

DOI
https://doi.org/10.1039/C3CC43723J
Article type
Communication
Submitted
17 May 2013
Accepted
25 Jun 2013
First published
26 Jun 2013

Chem. Commun., 2013,49, 7501-7503

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Palladium-catalyzed desulfitative hydroarylation of alkynes with sodium sulfinates

S. Liu, Y. Bai, X. Cao, F. Xiao and G. Deng, Chem. Commun., 2013, 49, 7501 DOI: 10.1039/C3CC43723J

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