Issue 68, 2013
From the journal:

Chemical Communications

Enhanced catalytic activity of titanosilicates controlled by hydrogen-bonding interactions†

Xiujuan Deng,a   Shuo Zhang,a   Binshen Wang,a   Yuning Wang,a   Haihong Wu,a   Yueming Liu*a  and  Mingyuan Hea  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai, China
E-mail: ymliu@chem.ecnu.edu.cn
Fax: +86-21 62232058

Abstract

A typical volcano-shaped curve has been found in heterogeneous catalytic systems containing titanosilicates for the first time. A new reactive intermediate with double H-bonds is proposed. Systematic results clearly evidence another H-bond formed between the high-electronegativity atom of the H-bond acceptor and the Hend atom of Ti–Oα–Oβ–Hend.

Graphical abstract: Enhanced catalytic activity of titanosilicates controlled by hydrogen-bonding interactions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC43372B
Article type
Communication
Submitted
07 May 2013
Accepted
17 Jun 2013
First published
17 Jun 2013

Chem. Commun., 2013,49, 7504-7506

Permissions

Request permissions

Enhanced catalytic activity of titanosilicates controlled by hydrogen-bonding interactions

X. Deng, S. Zhang, B. Wang, Y. Wang, H. Wu, Y. Liu and M. He, Chem. Commun., 2013, 49, 7504 DOI: 10.1039/C3CC43372B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements