Rate enhancement of hexose sugar oxidation on an ethynylpyridine-functionalized Pt/Al2O3 catalyst with induced chirality

Minoru Waki; Satoshi Muratsugu; Mizuki Tada

doi:10.1039/C3CC43482F

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Rate enhancement of hexose sugar oxidation on an ethynylpyridine-functionalized Pt/Al₂O₃catalyst with induced chirality†

Minoru Waki,‡^a Satoshi Muratsugu^ab and Mizuki Tada*^ab

Author affiliations

* Corresponding authors

^a Institute for Molecular Science, Nishigo-naka, Myodaiji, Okazaki, Aichi 444-8585, Japan

^b Department of Chemistry, Graduate School of Science/Research Center for Materials Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan
E-mail: mtada@chem.nagoya-u.ac.jp
Fax: +81-52-788-6200

Abstract

Rate enhancement of the selective oxidation of hexoses was achieved on an ethynylpyridine (EPy)-functionalized Pt/Al₂O₃ catalyst. Host–guest interaction between the EPy ligand and a hexose sugar reactant produced a complex with induced chirality on the catalyst surface.

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Article information

DOI: https://doi.org/10.1039/C3CC43482F
Article type: Communication
Submitted: 10 May 2013
Accepted: 21 Jun 2013
First published: 15 Jul 2013

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Chem. Commun., 2013,49, 7283-7285

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Rate enhancement of hexose sugar oxidation on an ethynylpyridine-functionalized Pt/Al₂O₃ catalyst with induced chirality

M. Waki, S. Muratsugu and M. Tada, Chem. Commun., 2013, 49, 7283 DOI: 10.1039/C3CC43482F

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Chemical Communications