Issue 36, 2013
From the journal:

Chemical Communications

Near-infrared room temperature emission from a novel class of Ru(ii) heteroleptic complexes with quinonoid organometallic linker†

Aurélie Damas,a   Maria Pia Gullo,b   Marie Noelle Rager,c   Anny Jutand,d   Andrea Barbierib  and  Hani Amouri*a  

* Corresponding authors

a Institut Parisien de Chimie Moléculaire, IPCM UMR CNRS 7201, Université Pierre et Marie Curie, Paris 6 4 place Jussieu, case 42, 75252 Paris Cedex 05, France
E-mail: hani.amouri@upmc.fr
Fax: +33 1-44-27-38-41

b Istituto per la Sintesi Organica e la Fotoreattività (ISOF), Consiglio Nazionale delle Ricerche (CNR), Via Gobetti 101, 40129 Bologna, Italy

c NMR Facilities of Ecole Nationale Supérieure de Chimie de Paris, 11 rue Pierre et Marie Curie, 75231 Paris Cedex 05, France

d Département de Chimie, UMR CNRS-ENS-UPMC 8640, 24 rue Lhomond, 75231 Paris Cedex 05, France

Abstract

A novel class of luminescent octahedral ruthenium complexes 2–4 displaying a π-bonded quinonoid ligand is described. Remarkably, the presence of this organometallic ligand affects their UV-vis properties and transforms them into panchromatic absorbers. Furthermore, it turns on room temperature NIR emissions.

Graphical abstract: Near-infrared room temperature emission from a novel class of Ru(ii) heteroleptic complexes with quinonoid organometallic linker

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Article information

DOI
https://doi.org/10.1039/C3CC41002A
Article type
Communication
Submitted
05 Feb 2013
Accepted
15 Mar 2013
First published
02 Apr 2013

Chem. Commun., 2013,49, 3796-3798

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Near-infrared room temperature emission from a novel class of Ru(II) heteroleptic complexes with quinonoid organometallic linker

A. Damas, M. P. Gullo, M. N. Rager, A. Jutand, A. Barbieri and H. Amouri, Chem. Commun., 2013, 49, 3796 DOI: 10.1039/C3CC41002A

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