Issue 36, 2013
From the journal:

Chemical Communications

Synthesis of sterically hindered xanthene-modified iron corroles with catalase-like activity†

Björn Zyskaa  and  Matthias Schwalbe*a  

* Corresponding authors

a Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, D-12489 Berlin, Germany
E-mail: matthias.schwalbe@hu-berlin.de
Fax: +49 30 2093 6966
Tel: +49 30 2093 7571

Abstract

An up to 18-fold increase of the turnover frequency (TOF) in the catalase-like hydrogen peroxide dismutation reaction is observed by incorporation of substituents in the β-position of xanthene-modified iron corroles.

Graphical abstract: Synthesis of sterically hindered xanthene-modified iron corroles with catalase-like activity

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Article information

DOI
https://doi.org/10.1039/C3CC40625C
Article type
Communication
Submitted
24 Jan 2013
Accepted
15 Mar 2013
First published
15 Mar 2013

Chem. Commun., 2013,49, 3799-3801

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Synthesis of sterically hindered xanthene-modified iron corroles with catalase-like activity

B. Zyska and M. Schwalbe, Chem. Commun., 2013, 49, 3799 DOI: 10.1039/C3CC40625C

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