Issue 4, 2013
From the journal:

Chemical Communications

Single electron transfer-induced Grignard cross-coupling involving ion radicals as exclusive intermediates†

Nanase Uchiyama,a   Eiji Shirakawa*a  and  Tamio Hayashi*b  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto, Japan
E-mail: shirakawa@kuchem.kyoto-u.ac.jp

b Institute of Materials Research and Engineering, 3, Research Link, Singapore
E-mail: tamioh@imre.a-star.edu.sg

Abstract

The mechanism of the previously developed cross-coupling reaction of aryl Grignard reagents with aryl halides was explored in more detail. Single electron transfer from an aryl Grignard reagent to an aryl halide initiates a radical chain by giving an anion radical of the aryl halide. The following propagation cycle consists entirely of anion radical intermediates.

Graphical abstract: Single electron transfer-induced Grignard cross-coupling involving ion radicals as exclusive intermediates

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC37643A
Article type
Communication
Submitted
20 Oct 2012
Accepted
15 Nov 2012
First published
15 Nov 2012

Chem. Commun., 2013,49, 364-366

Permissions

Request permissions

Single electron transfer-induced Grignard cross-coupling involving ion radicals as exclusive intermediates

N. Uchiyama, E. Shirakawa and T. Hayashi, Chem. Commun., 2013, 49, 364 DOI: 10.1039/C2CC37643A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements