Issue 20, 2012
From the journal:

RSC Advances

The first bromide ion directed double helicate and its role in catalysis†‡

P. M. Selvakumar,a   P. Yowan Jebaraj,a   Jashobanta Sahoo,a   E. Suresh,a   K. Jeya Prathap,a   R. I. Kureshy*a  and  P. S. Subramanian*a  

* Corresponding authors

a CSIR-Central Salt and Marine Chemicals Research Institute (Council of Scientific & Industrial Research), Bhavnagar–364 002, Gujarat, India
E-mail: siva@csmcri.org, rkureshy@csmcri.org
Fax: +91-278-25676970
Tel: +91-2782567760

Abstract

A bromide ion directed double stranded helicate is synthesised and its structure is reported for the first time. Synthesis of a series of β-aminocarbonyls using this water soluble helicate as a catalyst for a three-component amionalkylation reaction is also explored by adopting solvent-free reaction conditions.

Graphical abstract: The first bromide ion directed double helicate and its role in catalysis

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Article information

DOI
https://doi.org/10.1039/C2RA20507F
Article type
Paper
Submitted
20 Mar 2012
Accepted
25 May 2012
First published
15 Jun 2012

RSC Adv., 2012,2, 7689-7692

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The first bromide ion directed double helicate and its role in catalysis

P. M. Selvakumar, P. Y. Jebaraj, J. Sahoo, E. Suresh, K. J. Prathap, R. I. Kureshy and P. S. Subramanian, RSC Adv., 2012, 2, 7689 DOI: 10.1039/C2RA20507F

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