Electrophilicity of α-oxo gold carbene intermediates: halogen abstractions from halogenated solvents leading to the formation of chloro/bromomethyl ketones†
Abstract
α-Oxo gold
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* Corresponding authors
a
College of Chemistry and Chemical Engineering, State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha, P.R. of China
E-mail:
jnxiang@hnu.edu.cn
b
Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, United States
E-mail:
zhang@chem.ucsb.edu
Fax: +1 (805)893-4120
Tel: +1 (805)893-7392
α-Oxo gold
W. He, L. Xie, Y. Xu, J. Xiang and L. Zhang, Org. Biomol. Chem., 2012, 10, 3168 DOI: 10.1039/C2OB25235J
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