Jump to main content
Jump to site search

Issue 44, 2012
Previous Article Next Article

Self-assembly of [CuIITbIII]3+ and [W(CN)8]3− tectons: a case study of a mixture containing two complexes showing slow-relaxation of the magnetization

Author affiliations

Abstract

The reaction of [Cu(valen)] with Tb(NO3)3 and (Bu3NH)3[W(CN)8] affords two types of crystals: [{W(CN)8}Cu(valen)Tb(OH2)5]·2H2O (1, a discrete trinuclear complex) and [{W(CN)8}Cu(valen)Tb(OH2)4]·CH3CN·H2O (2, an infinite zig-zag chain), both compounds showing slow relaxation of the magnetization (H2valen is the Schiff base resulting from the reaction of o-vanillin with 1,2-ethanediamine).

Graphical abstract: Self-assembly of [CuIITbIII]3+ and [W(CN)8]3− tectons: a case study of a mixture containing two complexes showing slow-relaxation of the magnetization

Back to tab navigation

Supplementary files

Article information


Submitted
09 Sep 2012
Accepted
27 Sep 2012
First published
03 Oct 2012

Dalton Trans., 2012,41, 13578-13581
Article type
Communication

Self-assembly of [CuIITbIII]3+ and [W(CN)8]3− tectons: a case study of a mixture containing two complexes showing slow-relaxation of the magnetization

D. Visinescu, I. Jeon, A. M. Madalan, M. Alexandru, B. Jurca, C. Mathonière, R. Clérac and M. Andruh, Dalton Trans., 2012, 41, 13578
DOI: 10.1039/C2DT32081A

Social activity

Search articles by author

Spotlight

Advertisements