Slow magnetic relaxation in a 4,2-ribbon like FeIII2CoII heterobimetallic chain

Soonchul Kang; Shinji Kanegawa; Osamu Sato

doi:10.1039/C2DT31168B

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Slow magnetic relaxation in a 4,2-ribbon like Fe^III₂Co^II heterobimetallic chain†

Soonchul Kang,^a Shinji Kanegawa^a and Osamu Sato*^a

Author affiliations

* Corresponding authors

^a Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasuga-koen, Fukuoka, Japan
E-mail: sato@cm.kyushu-u.ac.jp
Tel: +81-92-583-7787

Abstract

The reaction of Co(NO₃)₂·6H₂O and 3-benzoylpyridine with the low-spin iron(III) complex, H[Fe^III(phen)(CN)₄], in methanol gives rise to a cyanide-bridged heterobimetallic chain [{Fe^III(phen)(CN)₄}₂Co^II(3-bpe)₂] (1) that exhibits intrachain ferromagnetic coupling and slow double magnetic relaxation.

This article is part of the themed collection: Frontier and Perspectives in Molecule-Based Quantum Magnet

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C2DT31168B
Article type: Communication
Submitted: 31 May 2012
Accepted: 24 Sep 2012
First published: 26 Sep 2012

Download Citation

Dalton Trans., 2012,41, 13575-13577

Permissions

Request permissions

Slow magnetic relaxation in a 4,2-ribbon like Fe^III₂Co^II heterobimetallic chain

S. Kang, S. Kanegawa and O. Sato, Dalton Trans., 2012, 41, 13575 DOI: 10.1039/C2DT31168B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions