Issue 23, 2012
From the journal:

CrystEngComm

Two novel entangled metal–organic networks constructed from 4,4′-bis(2-methylimidazol-1-ylmethyl)biphenyl and dicarboxylates: From polycatenated 2D + 2D → 3D framework to polyrotaxane-like 2D + 2D → 2D layer†

Di Sun,*a   Zhi-Hao Yan,ab   Yong-Kai Deng,a   Shuai Yuan,a   Lei Wang*b  and  Dao-Feng Suna  

* Corresponding authors

a Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, P. R. China
E-mail: dsun@sdu.edu.cn

b Key Laboratory of Eco-chemical Engineering, Ministry of Education, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, P. R. China
E-mail: inorchemwl@126.com

Abstract

Two novel entangled metal–organic networks, namely [Cd(bmimbp)(bdc)]n (1) and [Zn(bmimbp)(tbtpa)]n (2) (bmimbp = 4,4′-bis(2-methylimidazol-1-ylmethyl)biphenyl, H2bdc = 1,3-benzenedicarboxylic acid, H2tbtpa = tetrabromoterephthalic acid), exhibit a polycatenated 2D + 2D → 3D framework and a polyrotaxane-like 2D + 2D → 2D layer, respectively. Moreover, the thermal stabilities and photoluminescent properties are also discussed.

Graphical abstract: Two novel entangled metal–organic networks constructed from 4,4′-bis(2-methylimidazol-1-ylmethyl)biphenyl and dicarboxylates: From polycatenated 2D + 2D → 3D framework to polyrotaxane-like 2D + 2D → 2D layer

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Article information

DOI
https://doi.org/10.1039/C2CE25706H
Article type
Communication
Submitted
08 May 2012
Accepted
15 Aug 2012
First published
16 Aug 2012

CrystEngComm, 2012,14, 7856-7860

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Two novel entangled metal–organic networks constructed from 4,4′-bis(2-methylimidazol-1-ylmethyl)biphenyl and dicarboxylates: From polycatenated 2D + 2D → 3D framework to polyrotaxane-like 2D + 2D → 2D layer

D. Sun, Z. Yan, Y. Deng, S. Yuan, L. Wang and D. Sun, CrystEngComm, 2012, 14, 7856 DOI: 10.1039/C2CE25706H

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