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Issue 10, 2011
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Nanocatalysts for Suzuki cross-coupling reactions

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This critical review deals with the applications of nanocatalysts in Suzuki coupling reactions, a field that has attracted immense interest in the chemical, materials and industrial communities. We intend to present a broad overview of nanocatalysts for Suzuki coupling reactions with an emphasis on their performance, stability and reusability. We begin the review with a discussion on the importance of Suzuki cross-coupling reactions, and we then discuss fundamental aspects of nanocatalysis, such as the effects of catalyst size and shape. Next, we turn to the core focus of this review: the synthesis, advantages and disadvantages of nanocatalysts for Suzuki coupling reactions. We begin with various nanocatalysts that are based on conventional supports, such as high surface silica, carbon nanotubes, polymers, metal oxides and double hydroxides. Thereafter, we reviewed nanocatalysts based on non-conventional supports, such as dendrimers, cyclodextrin and magnetic nanomaterials. Finally, we discuss nanocatalyst systems that are based on non-conventional media, i.e., fluorous media and ionic liquids, for use in Suzuki reactions. At the end of this review, we summarise the significance of nanocatalysts, their impacts on conventional catalysis and perspectives for further developments of Suzuki cross-coupling reactions (131 references).

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Publication details

The article was received on 28 Mar 2011 and first published on 01 Aug 2011

Article type: Critical Review
DOI: 10.1039/C1CS15079K
Citation: Chem. Soc. Rev., 2011,40, 5181-5203

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    Nanocatalysts for Suzuki cross-coupling reactions

    A. Fihri, M. Bouhrara, B. Nekoueishahraki, J. Basset and V. Polshettiwar, Chem. Soc. Rev., 2011, 40, 5181
    DOI: 10.1039/C1CS15079K

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