Issue 10, 2011
From the journal:

Chemical Society Reviews

Transition metal-catalysed cross-coupling reactions of P-activated enols†

Jonathan D. Sellars*a  and  Patrick G. Steela  

* Corresponding authors

a Department of Chemistry, University of Durham, Science Laboratories, South Road, Durham, UK
E-mail: j.d.sellars@durham.ac.uk, p.g.steel@durham.ac.uk

Abstract

Transition metal catalysed cross-coupling reactions are ubiquitous in organic chemistry providing an impressive technique for C–C bond formation. Whilst many electrophilic partners have been described for these reactions, aryl and vinyl phosphates, phosphonates and phosphonites can offer advantages in terms of preparation, stability and reactivity profile. This critical review summarises the advances made to date utilising P-activated enols in metal-catalysed cross-coupling reactions (97 references).

Graphical abstract: Transition metal-catalysed cross-coupling reactions of P-activated enols

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Article information

DOI
https://doi.org/10.1039/C1CS15100B
Article type
Critical Review
Submitted
14 Apr 2011
First published
06 Jul 2011

Chem. Soc. Rev., 2011,40, 5170-5180

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Transition metal-catalysed cross-coupling reactions of P-activated enols

J. D. Sellars and P. G. Steel, Chem. Soc. Rev., 2011, 40, 5170 DOI: 10.1039/C1CS15100B

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