Issue 42, 2011
From the journal:

Chemical Communications

Amino acid functionalized metal–organic frameworks by a soft coupling–deprotection sequence†

Jerome Canivet,*a   Sonia Aguado,a   Gerard Bergereta  and  David Farrussenga  

* Corresponding authors

a Université Lyon 1, IRCELYON, Institut de Recherches sur la Catalyse et l'Environnement de Lyon, UMR CNRS 5256, avenue Albert Einstein 2, 69626 Villeurbanne, France
E-mail: jerome.canivet@ircelyon.univ-lyon1.fr
Fax: +33 (0)4 72 44 54 36
Tel: +33 (0)4 72 44 54 24

Abstract

Covalent post-synthetic modification of a MOF, (In) MIL-68-NH2, is carried out in a novel fashion to immobilize amino acids within the structure. Solid-phase peptide coupling methodology opens new perspectives for anchoring chiral bio- and catalytically active species. This could facilitate the immobilization of highly active and/or coordinating moieties inside MOF cavities.

Graphical abstract: Amino acid functionalized metal–organic frameworks by a soft coupling–deprotection sequence

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Article information

DOI
https://doi.org/10.1039/C1CC15541E
Article type
Communication
Submitted
07 Sep 2011
Accepted
21 Sep 2011
First published
30 Sep 2011

Chem. Commun., 2011,47, 11650-11652

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Amino acid functionalized metal–organic frameworks by a soft coupling–deprotection sequence

J. Canivet, S. Aguado, G. Bergeret and D. Farrusseng, Chem. Commun., 2011, 47, 11650 DOI: 10.1039/C1CC15541E

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