Issue 34, 2010
From the journal:

Dalton Transactions

Heterogeneous fullerene-supported osmium tetroxide catalyst for the cis-dihydroxylation of olefins†‡

Laura L. Lazarusa  and  Richard L. Brutchey*a  

* Corresponding authors

a Department of Chemistry, University of Southern California, Los Angeles, CA, USA
E-mail: brutchey@usc.edu

Abstract

We report on the activity of fullerene-supported OsO4 catalysts in the achiral dihydroxylation of olefins using N-methylmorpholine N-oxide as co-oxidant. The fullerene-supported OsO4 catalysts can selectively dihydroxylate olefins with conversions up to 95% after 48 h without leaching, and the catalysts can be recovered and recycled several times.

Graphical abstract: Heterogeneous fullerene-supported osmium tetroxide catalyst for the cis-dihydroxylation of olefins

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Article information

DOI
https://doi.org/10.1039/C0DT00599A
Article type
Communication
Submitted
03 Jun 2010
Accepted
23 Jun 2010
First published
13 Jul 2010

Dalton Trans., 2010,39, 7888-7890

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Heterogeneous fullerene-supported osmium tetroxide catalyst for the cis-dihydroxylation of olefins

L. L. Lazarus and R. L. Brutchey, Dalton Trans., 2010, 39, 7888 DOI: 10.1039/C0DT00599A

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