Issue 34, 2010
From the journal:

Dalton Transactions

Synthesis and structure of an aminoethyl-functionalized cyclopentadienyl vanadium(i) dinitrogen complex†

Guohua Liu,*a   Xiaohui Liang,a   Auke Meetsmab  and  Bart Hessenb  

* Corresponding authors

a The Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Normal University, Shanghai, China
E-mail: ghliu@shnu.edu.cn
Tel: + 86 21 64321819

b Center for Catalytic Olefin Polymerization, Stratingh Institute for Chemistry and Chemical Engineering, University of Groningen, Nijenborgh 4, Groningen, The Netherlands

Abstract

Reduction of a V(III) complex [(η5,η1-C5H4CH2CH2NMe2)VCl2(PMe3)] in the presence of diphenylacetylene under nitrogen atmosphere yields a novel V(I) dinitrogen-bridged complex {[η5-(C5H4CH2CH2NMe2)]V(PhC[triple bond, length as m-dash]CPh)(PMe3)}2(μ-N2).

Graphical abstract: Synthesis and structure of an aminoethyl-functionalized cyclopentadienyl vanadium(i) dinitrogen complex

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Article information

DOI
https://doi.org/10.1039/C0DT00499E
Article type
Communication
Submitted
19 May 2010
Accepted
08 Jul 2010
First published
26 Jul 2010

Dalton Trans., 2010,39, 7891-7893

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Synthesis and structure of an aminoethyl-functionalized cyclopentadienyl vanadium(I) dinitrogen complex

G. Liu, X. Liang, A. Meetsma and B. Hessen, Dalton Trans., 2010, 39, 7891 DOI: 10.1039/C0DT00499E

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