Issue 7, 2010

Hydrogen-bonded boron imidazolate frameworks

Abstract

The research on tetrahedral imidazolate frameworks takes on a new direction into the supramolecular area through the synthesis of three hydrogen-bonded boron imidazolate (B[im]4) frameworks (HBIFs) that show distinct three- and two-dimensional supramolecular architectures: (1) the ionic diamond net containing the first reported Li+ complex with ethylene glycol, (2) four-connected double-layers built from a new neutral Li(tea)B(im)4 (tea = triethanolamine) complex, and (3) three-connected (6,3) layer of H3O·BH(eim)3.

Graphical abstract: Hydrogen-bonded boron imidazolate frameworks

Supplementary files

Article information

Article type
Communication
Submitted
17 Jul 2009
Accepted
04 Dec 2009
First published
21 Dec 2009

Dalton Trans., 2010,39, 1702-1704

Hydrogen-bonded boron imidazolate frameworks

J. Zhang, T. Wu, P. Feng and X. Bu, Dalton Trans., 2010, 39, 1702 DOI: 10.1039/B924633A

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