Issue 5, 2010
From the journal:

Dalton Transactions

A double-stranded dinuclear cadmium(ii) helicate that assembles into chains in the solid state†‡

Miguel Martínez-Calvo,a   Ana M. González-Noya,*b   Rosa Pedrido,a   María J. Romero,a   M. Isabel Fernández,b   Guillermo Zaragozac  and  Manuel R. Bermejo*a  

* Corresponding authors

a Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, Santiago de Compostela, Galicia, Spain
E-mail: manuel.bermejo@usc.es
Fax: +34 981597525
Tel: +34 981563100

b Departamento de Química Inorgánica, Facultade de Ciencias, Universidade de Santiago de Compostela, Lugo, Galicia, Spain
E-mail: ana.gonzalez.noya@usc.es
Fax: +34 981597525
Tel: +34 981563100

c Unidade de Difracción de Raios X. Edificio CACTUS. Universidade de Santiago de Compostela, Campus Sur, Santiago de Compostela, Galicia, Spain

Abstract

A [4+4] double-stranded cadmium dihelicate was afforded from an easily accessible thiosemicarbazone ligand; its crystal structure reveals the assembly of two enantiomers into dihelicate pairs, these pairs being further connected into infinite linear chains.

Graphical abstract: A double-stranded dinuclear cadmium(ii) helicate that assembles into chains in the solid state

  • This article is part of the themed collection: FIGIPAS 2009
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Article information

DOI
https://doi.org/10.1039/B915953C
Article type
Communication
Submitted
04 Aug 2009
Accepted
24 Oct 2009
First published
10 Nov 2009

Dalton Trans., 2010,39, 1191-1194

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A double-stranded dinuclear cadmium(II) helicate that assembles into chains in the solid state

M. Martínez-Calvo, A. M. González-Noya, R. Pedrido, M. J. Romero, M. I. Fernández, G. Zaragoza and M. R. Bermejo, Dalton Trans., 2010, 39, 1191 DOI: 10.1039/B915953C

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