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Issue 35, 2010
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Room-temperature spin crossover and Langmuir–Blodgett film formation of an iron(II) triazole complex featuring a long alkyl chain substituent: the tail that wags the dog

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Abstract

[FeII(C16dpt)2(NCS)2]·⅔H2O displays temperature-mediated spin crossover (SCO) with T½ = 290 K and the long alkyl chain substituent on the dipyridyltriazole ligand facilitates the formation of a stable Langmuir–Blodgett film at an air–water interface.

Graphical abstract: Room-temperature spin crossover and Langmuir–Blodgett film formation of an iron(ii) triazole complex featuring a long alkyl chain substituent: the tail that wags the dog

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Publication details

The article was received on 19 Apr 2010, accepted on 17 Jun 2010 and first published on 07 Jul 2010


Article type: Communication
DOI: 10.1039/C0CC01008A
Citation: Chem. Commun., 2010,46, 6464-6466
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    Room-temperature spin crossover and Langmuir–Blodgett film formation of an iron(II) triazole complex featuring a long alkyl chain substituent: the tail that wags the dog

    J. A. Kitchen, N. G. White, C. Gandolfi, M. Albrecht, G. N. L. Jameson, J. L. Tallon and S. Brooker, Chem. Commun., 2010, 46, 6464
    DOI: 10.1039/C0CC01008A

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