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Issue 6, 2010
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Diastereoselective and enantioselective Mukaiyama aldol reactions of α-ketoesters using hydrogen bond catalysis

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Abstract

Hydrogen bond catalyzed Mukaiyama aldol reactions of α-ketoesters proceed in high diastereo- and enantioselectivities, giving products possessing two chiral centers, of which one is a tertiary alcohol.

Graphical abstract: Diastereoselective and enantioselective Mukaiyama aldol reactions of α-ketoesters using hydrogen bond catalysis

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Publication details

The article was received on 24 Sep 2009, accepted on 17 Dec 2009 and first published on 11 Jan 2010


Article type: Communication
DOI: 10.1039/B919929B
Citation: Chem. Commun., 2010,46, 904-906

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    Diastereoselective and enantioselective Mukaiyama aldol reactions of α-ketoesters using hydrogen bond catalysis

    V. B. Gondi, K. Hagihara and V. H. Rawal, Chem. Commun., 2010, 46, 904
    DOI: 10.1039/B919929B

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