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Issue 6, 2010
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Enantiomerically pure β-phenylalanine analogues from α–β-phenylalanine mixtures in a single reactive extraction step

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Abstract

An efficient and selective method for the extraction of α-amino acids in preference over their β-isomers using PdCl2(PPh3)2 was discovered, which enables the separation of product mixtures obtained in the enantioselective enzymatic formation of β-amino acids.

Graphical abstract: Enantiomerically pure β-phenylalanine analogues from α–β-phenylalanine mixtures in a single reactive extraction step

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Article information


Submitted
16 Oct 2009
Accepted
12 Nov 2009
First published
04 Dec 2009

Chem. Commun., 2010,46, 901-903
Article type
Communication

Enantiomerically pure β-phenylalanine analogues from α–β-phenylalanine mixtures in a single reactive extraction step

B. J. V. Verkuijl, W. Szymański, B. Wu, A. J. Minnaard, D. B. Janssen, J. G. de Vries and B. L. Feringa, Chem. Commun., 2010, 46, 901
DOI: 10.1039/B921661H

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