Issue 36, 2010
From the journal:

Chemical Communications

Synthesis of a 1-boratabenzene-(2,3,4,5-tetramethylphosphole): towards a planar monophosphole†‡

Guillaume Bélanger-Chabot,a   Philippe Rioux,a   Laurent Maron*b  and  Frédéric-Georges Fontaine*a  

* Corresponding authors

a Département de chimie, Université Laval, 1045 Avenue de la Médecine Cité Universitaire, Québec, Qc, Canada
E-mail: frederic.fontaine@chm.ulaval.ca
Fax: +1 418 6565140

b Université de Toulouse, INSA, UPS, LPCNO, CNRS, LPCNO, UMR 5215 CNRS-UPS-INSA, 135 avenue de Rangueil, 31077 Toulouse, France

Abstract

Novel boratabenzene–phosphole complexes have been prepared and structurally characterized. The electronic communication between the two heterocyclic rings linked by a P–B bond and the aromaticity of these systems were probed using crystallographic and density functional studies.

Graphical abstract: Synthesis of a 1-boratabenzene-(2,3,4,5-tetramethylphosphole): towards a planar monophosphole

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Article information

DOI
https://doi.org/10.1039/C0CC01999B
Article type
Communication
Submitted
21 Jun 2010
Accepted
16 Jul 2010
First published
16 Aug 2010

Chem. Commun., 2010,46, 6816-6818

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Synthesis of a 1-boratabenzene-(2,3,4,5-tetramethylphosphole): towards a planar monophosphole

G. Bélanger-Chabot, P. Rioux, L. Maron and F. Fontaine, Chem. Commun., 2010, 46, 6816 DOI: 10.1039/C0CC01999B

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