Issue 35, 2010
From the journal:

Chemical Communications

Room-temperature spin crossover and Langmuir–Blodgett film formation of an iron(ii) triazole complex featuring a long alkyl chain substituent: the tail that wags the dog†

Jonathan A. Kitchen,a   Nicholas G. White,a   Claudio Gandolfi,b   Martin Albrecht,bc   Guy N. L. Jameson,a   Jeffery L. Tallond  and  Sally Brooker*a  

* Corresponding authors

a Department of Chemistry and MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, PO Box 56, Dunedin 9054, New Zealand
E-mail: sbrooker@chemistry.otago.ac.nz

b Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg, Switzerland

c School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland

d MacDiarmid Institute for Advanced Materials and Nanotechnology and Industrial Research Limited, PO Box 31310, Lower Hutt, New Zealand

Abstract

[FeII(C16dpt)2(NCS)2]·⅔H2O displays temperature-mediated spin crossover (SCO) with T½ = 290 K and the long alkyl chain substituent on the dipyridyltriazole ligand facilitates the formation of a stable Langmuir–Blodgett film at an air–water interface.

Graphical abstract: Room-temperature spin crossover and Langmuir–Blodgett film formation of an iron(ii) triazole complex featuring a long alkyl chain substituent: the tail that wags the dog

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Article information

DOI
https://doi.org/10.1039/C0CC01008A
Article type
Communication
Submitted
19 Apr 2010
Accepted
17 Jun 2010
First published
07 Jul 2010

Chem. Commun., 2010,46, 6464-6466

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Room-temperature spin crossover and Langmuir–Blodgett film formation of an iron(II) triazole complex featuring a long alkyl chain substituent: the tail that wags the dog

J. A. Kitchen, N. G. White, C. Gandolfi, M. Albrecht, G. N. L. Jameson, J. L. Tallon and S. Brooker, Chem. Commun., 2010, 46, 6464 DOI: 10.1039/C0CC01008A

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