Issue 31, 2010
From the journal:

Chemical Communications

Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes†

Christine M. Thomas,*a   J. Wesley Napoline,a   Gerard T. Rowea  and  Bruce M. Foxmana  

* Corresponding authors

a Department of Chemistry, Brandeis University, 415 South Street, Waltham, USA
E-mail: thomasc@brandeis.edu
Fax: +1 781-736-2516
Tel: +1 781-736-2576

Abstract

The reactivity of heterobimetallic Zr/Co complexes linked by phosphinoamide ligands towards the oxidative addition of I2 and alkyl halides is reported. These reactions are accompanied by dissociation of one phosphine ligand from Co and η2-coordination to Zr. Addition of H2 leads to both oxidative addition across the M–M bond and P–N bond cleavage.

Graphical abstract: Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CC01272F
Article type
Communication
Submitted
07 May 2010
Accepted
10 Jun 2010
First published
24 Jun 2010

Chem. Commun., 2010,46, 5790-5792

Permissions

Request permissions

Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes

C. M. Thomas, J. W. Napoline, G. T. Rowe and B. M. Foxman, Chem. Commun., 2010, 46, 5790 DOI: 10.1039/C0CC01272F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements