In situ hydrogen from aqueous-methanol for nitroarene reduction and imine formation over an Au–Pd/Al2O3 catalyst

Yizhi Xiang; Qiangqiang Meng; Xiaonian Li; Jianguo Wang

doi:10.1039/C0CC00531B

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In situhydrogen from aqueous-methanol for nitroarenereduction and imine formation over an Au–Pd/Al₂O₃catalyst†

Yizhi Xiang,^a Qiangqiang Meng,^a Xiaonian Li*^a and Jianguo Wang^a

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* Corresponding authors

^a State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Industrial Catalysis Institute of Zhejiang University of Technology, Hangzhou 310032, P.R. China
E-mail: xnli@zjut.edu.cn
Fax: +86 571-88320409
Tel: +86 571-88320409

Abstract

In situ hydrogen from aqueous-methanol, instead of H₂ or CO, was used to synthesize imines with a high selectivity from nitroarenes and carbonyl compounds over an Au–Pd/Al₂O₃ catalyst.

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Supplementary files

Experimental procedures, catalyst evaluation, DFT calculations. PDF (645K)

Article information

DOI: https://doi.org/10.1039/C0CC00531B
Article type: Communication
Submitted: 22 Mar 2010
Accepted: 07 Jun 2010
First published: 07 Jul 2010

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Chem. Commun., 2010,46, 5918-5920

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In situ hydrogen from aqueous-methanol for nitroarene reduction and imine formation over an Au–Pd/Al₂O₃ catalyst

Y. Xiang, Q. Meng, X. Li and J. Wang, Chem. Commun., 2010, 46, 5918 DOI: 10.1039/C0CC00531B

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