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Abstract | Cited by

A Ni(0)-catalyzed Tishchenko reaction which can be applied to a variety of aliphatic aldehydes (1°, 2°, 3°) and aromatic aldehydes was developed. The reaction might proceed via a hetero-nickelacycle intermediate.

Graphical abstract: Nickel-catalyzed Tishchenko reaction via hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complex

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