Issue 16, 2010
From the journal:

Chemical Communications

Asymmetric catalyticemulsion polymerization in chiral micelles†

Xiaofeng Luo,ab   Lei Li,ab   Jianping Deng,*ab   Tiantian Guob  and  Wantai Yang*ab  

* Corresponding authors

a State Key Laboratory of Chemical Resource Engineering, Beijing 100029, China

b College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
E-mail: dengjp@mail.buct.edu.cn, yangwt@mail.buct.edu.cn
Fax: +86-10-6443-5128
Tel: +86-10-6443-5128

Abstract

Achiral substituted acetylene monomers undergo aqueous catalytic emulsion asymmetric polymerizations in chiral micelles consisting of SDS and amino acid, providing optically active helical polymer emulsions. The asymmetric polymerizations lead to one-handed helical polymers, which are the origin of the optical activity of polymer emulsions.

Graphical abstract: Asymmetric catalytic emulsion polymerization in chiral micelles

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Article information

DOI
https://doi.org/10.1039/B926134F
Article type
Communication
Submitted
11 Dec 2009
Accepted
05 Mar 2010
First published
17 Mar 2010

Chem. Commun., 2010,46, 2745-2747

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Asymmetric catalytic emulsion polymerization in chiral micelles

X. Luo, L. Li, J. Deng, T. Guo and W. Yang, Chem. Commun., 2010, 46, 2745 DOI: 10.1039/B926134F

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