Issue 35, 2009
From the journal:

Dalton Transactions

N-heterocyclic carbenes of iridium(I): ligand effects on the catalytic activity in transfer hydrogenation†

Sandra C. Zinner,a   Christoph F. Rentzsch,a   Eberhardt Herdtweck,a   Wolfgang A. Herrmann*a  and  Fritz. E. Kühn*ab  

* Corresponding authors

a Chair of Inorganic Chemistry, Department of Chemistry, Technische Universität München, Lichtenbergstraße 4, Garching, Germany
E-mail: wolfgang.herrmann@ch.tum.de

b Molecular Catalysis, Catalysis Research Center, Technische Universität München, Lichtenbergstraße 4, Garching, Germany
E-mail: fritz.kuehn@ch.tum.de

Abstract

New Ir-NHC complexes based on different heterocyclic moieties like imidazole, benzimidazole and imidazolidine are presented and tested in transfer hydrogenation catalysis. A broad range of steric and electronic properties of NHC ligands is covered to give an idea for catalyst design from the experimental point of view.

Graphical abstract: N-heterocyclic carbenes of iridium(I): ligand effects on the catalytic activity in transfer hydrogenation

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Article information

DOI
https://doi.org/10.1039/B906855D
Article type
Paper
Submitted
06 Apr 2009
Accepted
15 Jun 2009
First published
14 Jul 2009

Dalton Trans., 2009, 7055-7062

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N-heterocyclic carbenes of iridium(I): ligand effects on the catalytic activity in transfer hydrogenation

S. C. Zinner, C. F. Rentzsch, E. Herdtweck, W. A. Herrmann and Fritz. E. Kühn, Dalton Trans., 2009, 7055 DOI: 10.1039/B906855D

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