Issue 18, 2009
From the journal:

Dalton Transactions

Iridium tricarbido complexes viatransmetallation with tricarbidomercurials†

Rian D. Dewhurst,a   Anthony F. Hill*a  and  Anthony C. Willisa  

* Corresponding authors

a Research School of Chemistry, Institute of Advanced Studies, Australian National University, Canberra, Australian Capital Territory, Australia
E-mail: a.hill@anu.edu.au
Fax: +61 2 6125 3216

Abstract

The reactions of Vaska's complex with [Hg{C[triple bond, length as m-dash]CC[triple bond, length as m-dash]W(CO)2(L)}2] (L = HB(pz)3, HB(pzMe2)3, pz = pyrazol-1-yl) unexpectedly provide the structurally characterized tetrametallic trans-bis(tricarbido)complex [Ir(HgCl){C[triple bond, length as m-dash]CC[triple bond, length as m-dash]W(CO)2(L)}2(CO)(PPh3)2].

Graphical abstract: Iridium tricarbido complexes viatransmetallation with tricarbidomercurials

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Article information

DOI
https://doi.org/10.1039/B900205G
Article type
Communication
Submitted
06 Jan 2009
Accepted
27 Feb 2009
First published
10 Mar 2009

Dalton Trans., 2009, 3384-3387

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Iridium tricarbido complexes viatransmetallation with tricarbidomercurials

R. D. Dewhurst, A. F. Hill and A. C. Willis, Dalton Trans., 2009, 3384 DOI: 10.1039/B900205G

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