Issue 18, 2009

The transition metal hexafluorides

Abstract

The nine transition metal hexafluorides present a unique series of closely related compounds. Deviations from octahedral structures are influenced by Jahn–Teller effects and spin orbit coupling. The most pronounced chemical behaviour is the increasing electron affinity in the direction WF6→ PtF6 and MoF6→ RuF6, so that with PtF6 and RuF6 values of 7 eV or higher are reached. All hexafluorides can be used as one electron oxidants, starting with mild (WF6) up to extreme (PtF6, RuF6) oxidation power.

Graphical abstract: The transition metal hexafluorides

Article information

Article type
Perspective
Submitted
26 Nov 2008
Accepted
05 Jan 2009
First published
18 Feb 2009

Dalton Trans., 2009, 3379-3383

The transition metal hexafluorides

M. J. Molski and K. Seppelt, Dalton Trans., 2009, 3379 DOI: 10.1039/B821121C

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